BENZYLATION OF ALCOHOLS TO BENZYL ETHERS WITH ALKALI CATION EXCHANGED Y TYPE ZEOLITE
نویسندگان
چکیده
منابع مشابه
Retro-Claisen benzylation: direct use of benzyl alcohols in Pd-catalyzed couplings with nitriles.
A new strategy has been developed for the benzylation of nitriles directly from benzyl alcohols. In this process benzyl alcohols undergo retro-Claisen activation with cyanoacetic esters to generate an active electrophile and a carbanionic nucleophile. In the presence of Pd(0) these intermediates undergo catalytic coupling to generate a new C-C bond, resulting in the formation of phenyl propioni...
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ژورنال
عنوان ژورنال: Chemistry Letters
سال: 1983
ISSN: 0366-7022,1348-0715
DOI: 10.1246/cl.1983.1101